SCHEDULED MAINTENANCE
The putative intermediates in brassinolide biosynthesis, 22α-hydroxycampesterol 1, 6-deoxocathasterone and its 6α-hydroxylated compound 3, as well as cathasterone 4, are synthesized from a known (22E,24S)-6β-methoxy-3α,5-cyclo-5α-ergost-22-ene 5.
S. Takatsuto, H. Kuriyama, T. Noguchi, H. Suganuma, S. Fujioka and A. Sakurai, J. Chem. Res. (S), 1997, 418 DOI: 10.1039/A704788F
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