NMR Spectroscopic Correlations for a Series of Triangularµ-Oxoruthenium Acetate Clusters containing SubstitutedPyridine Ligands†
Abstract
The
1
H and
13
C NMR chemicalshifts of the acetate and pyridine ligands α-position) in aseries of[Ru
3
O(CH
3
CO
2
)
6
L
3
]
+
clusters are linearly correlated with thepK
a
(L), but exhibit variable trends at thevarious positions as a consequence of the inductive, paramagneticanisotropy and ring current effectsand the ligand interactionsthrough the Ru
3
O core.
Please wait while we load your content...
