Issue 3, 1997

Bis(quinolin-8-olato) Complexes of Ruthenium. Synthesis, Characterization and Cyclic Voltammetric Studies†

Abstract

Reaction of quinolin-8-ol (HQ) with [Ru(bpy)Cl 3 ] (bpy=2,2′-bipyridine) in the presence of NEt 3 affords [Ru II (bpy)(Q) 2 ] which shows a Ru II –Ru III oxidation at -0.16 V vs. SCE and a Ru III –Ru IV oxidation at 1.06 V vs. SCE; its oxidation by Ce 4+ gives [Ru III (bpy)(Q) 2 ] + which has been isolated and characterized as the perchlorate salt.

Article information

Article type
Paper

J. Chem. Res. (S), 1997, 98-99

Bis(quinolin-8-olato) Complexes of Ruthenium. Synthesis, Characterization and Cyclic Voltammetric Studies†

N. Chand Pramanik and S. Bhattacharya, J. Chem. Res. (S), 1997, 98 DOI: 10.1039/A605408K

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