Macropolyhedral boron-containing cluster chemistry. Assessment of the
possibilities of thermolytic mixed-cluster fusion, and of the use of
synchrotron X-radiation for the examination of small single crystals of
metallaboranes. Isolation and structure of eighteen-vertex
[7-(CO)-7,7-(PMe3)2-syn-7-IrB17
H20]
Abstract
Thermolysis of
[(CO)(PMe
3
)
2
HIrB
8
H
12
] with
molten B
10
H
14
resulted in small yields of
eighteen-vertex
[7-(CO)-7,7-(PMe
3
)
2
-syn-7-IrB
17
H
20
] for which a small crystal was examined by
single-crystal diffraction analysis, using synchrotron X-radiation, in
order to determine the molecular structure.
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