Synthesis of new amido, alkoxo and η-cyclopentadienyl
derivatives of molybdenum
Abstract
The new compounds
[Mo(η-Me
3
SiC
5
H
4
)(NMe
2
)
3
]
,
[Mo(η-Me
3
SiC
5
H
4
)
2
H
2
],
[Mo(η-C
9
H
7
)(NMe
2
)
3
],
[Mo(η-C
5
H
5
)(S
2
CNMe
2
)
3
],
[Mo(η-C
5
H
5
)(OPr
i
)(NMe
2
)
2
],
[Mo(η-C
5
H
5
)(OPr
i
)
2
(NMe
2
)],
[Mo(η-C
5
H
5
)(OBu
t
)(NMe
2
)
2
],
[Mo(η-C
5
H
5
)(OBu
t
)
2
(NMe
2
)],
[Mo(η-C
5
H
5
)(OC
6
H
2
Me-4-
Bu
t
2
-2,6)(NMe
2
)
2
],
[Mo(η-C
5
H
5
)(OC
6
H
3
Me-6-
Bu
t
-2)(NMe
2
)
2
],
[Mo(η-C
5
H
5
)(OC
6
H
4
Bu
t
-p)(NMe
2
)
2
],
[Mo(OR)
4
(HNMe
2
)
2
]
(R = p-MeC
6
H
4
* or
p-Bu
t
C
6
H
4
) and
[Mo(OC
6
H
4
Me-p)
4
(NMe
2
)
2
]* have been prepared and characterised. The
asterisk indicates the crystal structure has been determined.
* or
p-Bu
t
C
6
H
4
) and
[Mo(OC
6
H
4
Me-p)
4
(NMe
2
)
2
]* have been prepared and characterised. The
asterisk indicates the crystal structure has been determined.
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