Issue 6, 1997

Synthesis and applications of [Au(NCPh)2]+, a versatile labile gold(I) intermediate

Abstract

The [Au(NCPh) 2 ] + cation has been isolated and synthesized in high yields by the oxidation of gold powder in the presence of NOBF 4 . It represents a labile form of gold(I), which has been shown to be a valuable synthon for the synthesis of a wide range of gold(I) complexes and especially of a variety of gold(I) amines which have opened new synthetic routes for the isolation of organometallic gold(I) complexes.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1997, 1103-1112

Synthesis and applications of [Au(NCPh)2]+, a versatile labile gold(I) intermediate

J. Yau and D. Michael P. Mingos, J. Chem. Soc., Dalton Trans., 1997, 1103 DOI: 10.1039/A606207E

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