In contrast to previous assumptions, the isoquinoline alkaloid (S)-norreticuline is the biosynthetic precursor to Erythrina alkaloids and, furthermore, this precursor is asymmetrically incorporated into these spirocyclic alkaloids.
U. H. Maier and M. H. Zenk, Chem. Commun., 1997, 2313 DOI: 10.1039/A706595G
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