Issue 24, 1997

Catalytic and asymmetric aziridination of alkenes catalysed by a chiral manganese porphyrin complex

Abstract

A D4-manganese(III) porphyrin is utilized to catalyze aziridination of styrene-type substrates with enantiomeric excess ranging from 43 to 68%; evidence for a MnIV reactive intermediate in the catalysis was obtained from spectroscopic studies and organic product analysis.

Article information

Article type
Paper

Chem. Commun., 1997, 2373-2374

Catalytic and asymmetric aziridination of alkenes catalysed by a chiral manganese porphyrin complex

T. Lai, C. Che, H. Kwong and S. Peng, Chem. Commun., 1997, 2373 DOI: 10.1039/A706395D

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