A tungsten–η1-vinylprop-2-ynyl compound undergoes enantioselective aminocarbonylation to afford an optically pure tungsten–π-γ-lactone; this π-allyl complex is useful for the efficient synthesis of optically pure α-methylene butyrolactone.
L. Hung Shiu, S. Wang, R. Liu and M. Wu, Chem. Commun., 1997, 2055 DOI: 10.1039/A706309A
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