An attractive intramolecular 1,5-CH···O interaction is evidenced in a conformer of 1-methoxy-2-(methylthio)ethane, in which the distance between a hydrogen atom of the SMe group and the oxygen atom is significantly shorter than the van der Waals separation.
H. Yoshida, Chem. Commun., 1997, 2213 DOI: 10.1039/A706029G
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