An asymmetric Diels–Alder reaction between 1-phenyl-3,4-dimethylphosphole and ethyl vinyl ketone promoted by a chiral organopalladium complex gives the corresponding keto-substituted phosphine ligands in which the keto group can be stereospecifically located in the endo- or exo-positions of the phosphanorbornene skeleton.
P. Leung, S. Loh, J. J. Vittal, A. J. P. White and D. J. Williams, Chem. Commun., 1997, 1987 DOI: 10.1039/A705830F
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