The molecular structure of (R,S)-[Al6But6(µ3-O)4{µ3-O2CCH2C(H)(Me)O}2]: evidence for the latent Lewis acid catalyzed polymerization of (R,S)-β-butyrolactone

Abstract

The reaction of [Bu^tAl(µ₃-O)]₆ with 2 equiv. of (R,S)-β-butyrolactone resulted in the formation of the alumoxane, (R,S)-[Al₆Bu^t₆(µ₃-O)₄{µ₃-O₂CCH₂C(H)(Me)O}₂], with a molecular structure consisting of two ring-opened lactone moieties inserted into, and bridging, the edge of the Al₆O₆ alumoxane. The role of this alumoxane in the latent Lewis acid catalyzed ring-opening polymerization of β-butyrolactone is discussed.