T
i(µ:η1,η1-OCMe2CH2PPh2)3R
h has a cylindrically symmetric triple bond
Abstract
The cylindrical symmetry of Ti(µ:η1,η1-OCMe2CH2- PPh2)3R
h permits maximum Rh(dπ) → Ti(d/pπ) overlap, resulting in a 2.2142(11) Å metal–metal triple bond.