Issue 19, 1997
From the journal:

Chemical Communications

Differing degrees of five-coordination for similar tin atoms in the polymetallic complex [(OC)3Fe[upper bond 1 start][lower bond 1 start](µ-Ph2Ppy)(S[lower bond 1 end]nPh2)(µ-Cl)(S[upper bond 1 end]nClPh2)]

Pierre Braunstein,   Chantal Charles,   Pierre Braunstein,   Chantal Charles,   Guido Kickelbick  and  Ulrich Schubert  

Abstract

The unusual iron–bistin complex, [(OC)3F[upper bond 1 start][lower bond 1 start]e(µ-Ph2Ppy)(S[lower bond 1 end]nPh2)(µ-Cl(S[upper bond 1 end]nClPh2)], obtained by silicon–tin exchange from a Si–Fe–Sn precursor, contains two tin atoms showing different degrees of five-coordination, a unique feature of relevance to hypercoordination of main-group elements.

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Article information

DOI
https://doi.org/10.1039/A704749E
Article type
Paper

Chem. Commun., 1997, 1911-1912

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Differing degrees of five-coordination for similar tin atoms in the polymetallic complex [(OC)3Fe[upper bond 1 start][lower bond 1 start](µ-Ph2Ppy)(S[lower bond 1 end]nPh2)(µ-Cl)(S[upper bond 1 end]nClPh2)]

P. Braunstein, C. Charles, P. Braunstein, C. Charles, G. Kickelbick and U. Schubert, Chem. Commun., 1997, 1911 DOI: 10.1039/A704749E

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