Issue 16, 1997

Highly selective trimerisation of MeNC by a novel titanium imido complex containing a tridentate dianionic ligand

Abstract

A new type of imido compound [Ti(NBu t )L(py)] 1 containing a tripodal dianionic ligand is reported which effects the remarkably selective trimerisation of MeNC; the crystal structures of 1 and [TiL{N(Me)N(Bu t )(C 4 H 3 N 2 M e)}] 2 are described [L = MeC(2-C 5 H 4 N)(CH 2 NSiMe 3 ) 2 ].

Article information

Article type
Paper

Chem. Commun., 1997, 1555-1556

Highly selective trimerisation of MeNC by a novel titanium imido complex containing a tridentate dianionic ligand

A. J. Blake, P. E. Collier, L. H. Gade, M. McPartlin, P. Mountford, M. Schubart and I. J. Scowen, Chem. Commun., 1997, 1555 DOI: 10.1039/A703275G

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