Issue 14, 1997
From the journal:

Chemical Communications

Tandem insertion of allenyl carbenoids and aldehydes into zirconacycles: an unexpected cyclisation

George J. Gordon  and  Richard J. Whitby  

Abstract

Allenyl carbenoids (3-chloro-1-lithioalk-1-ynes) insert into zirconacyclopentanes and zirconacyclopentenes to afford cyclic η 3 -allenyl/prop-2-ynyl zirconocene complexes which give allenyl, alkynyl or cyclised-alcohol products on addition of aldehydes activated with boron trifluoride–diethyl ether.

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Article information

DOI
https://doi.org/10.1039/A702732J
Article type
Paper

Chem. Commun., 1997, 1321-1322

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Tandem insertion of allenyl carbenoids and aldehydes into zirconacycles: an unexpected cyclisation

G. J. Gordon and R. J. Whitby, Chem. Commun., 1997, 1321 DOI: 10.1039/A702732J

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