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Issue 11, 1997
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1H-Phosphiranes and -enes invert at phosphorus via a turnstile rotation

Abstract

Ab initio (CCSD(T)/6-31+G*) calculations suggest that 1H-phosphiranes and 1H-phosphirenes invert their configuration at phosphorus by a rotation of the PX group (X = H, F, Cl, Br) above the C 2 moiety, rather than the more usual planar trigonal inversion pathway via a C 2v transition state.

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Article information


Chem. Commun., 1997, 1033-1034
Article type
Paper

1H-Phosphiranes and -enes invert at phosphorus via a turnstile rotation

A. Göller and T. Clark, Chem. Commun., 1997, 1033
DOI: 10.1039/A701788J

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