Issue 9, 1997

First mononuclear organometallics of MoII and MoIII containing terminal hydroxide ligands. X-Ray structure of [Mo(η5-C5H5)(OH)(PMe3) 3]BF4

Abstract

The new complexes [Mo(η 5 -C 5 H 5 )(OH)(PMe 3 ) 2 ] and [Mo(η 5 -C 5 H 5 )(OH)(PMe 3 ) 3 ] + are unique examples of electronically unsaturated organometallics of Mo II and Mo III containing terminal hydroxide ligands; they show no tendency to dimerize with formation of hydroxo-bridges.

Article information

Article type
Paper

Chem. Commun., 1997, 889-890

First mononuclear organometallics of MoII and MoIII containing terminal hydroxide ligands. X-Ray structure of [Mo(η5-C5H5)(OH)(PMe3) 3]BF4

J. C. Fettinger, H. Kraatz, R. Poli and E. Alessandra Quadrelli, Chem. Commun., 1997, 889 DOI: 10.1039/A701616F

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