Issue 9, 1997

Isonitrile–nitrile rearrangement promoted by samarium(ii) iodide

Abstract

A samarium(II) iodide-promoted rearrangement of isonitriles to nitriles, which requires an α-alkoxycarbonyl group at the carbon atom bearing the isonitrile group, occurs under very mild conditions and contrasts with the thermal version of the rearrangement, which usually requires high temperature.

Article information

Article type
Paper

Chem. Commun., 1997, 821-822

Isonitrile–nitrile rearrangement promoted by samarium(ii) iodide

H. Kang, A. Nim Pae, Y. Seo Cho, H. Yeong Koh and B. Young Chung, Chem. Commun., 1997, 821 DOI: 10.1039/A700570I

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