Issue 7, 1997
From the journal:

Chemical Communications

Excited state carbon acids: irreversible photodeprotonation of the benzylic protons of 10-methyl- and 10-phenyl-thioxanthenium salts

Darryl Brousmiche,   Deepak Shukla  and  Peter Wan  

Abstract

The first examples of irreversible photodeprotonation of a C–H bond to generate a formal carbanion, via photolysis of thioxanthenium salts, is reported, which gives the corresponding sulfonium ylide (thiaanthracene) and acid (HBF 4 or HClO 4 ).

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Article information

DOI
https://doi.org/10.1039/A608434F
Article type
Paper

Chem. Commun., 1997, 709-710

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Excited state carbon acids: irreversible photodeprotonation of the benzylic protons of 10-methyl- and 10-phenyl-thioxanthenium salts

D. Brousmiche, D. Shukla and P. Wan, Chem. Commun., 1997, 709 DOI: 10.1039/A608434F

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