Issue 3, 1997

Anomalous role of molecular sieves 4A in the preparation of a binaphthol-derived active µ3-oxo titanium catalyst

Abstract

The active species of binaphthol-derived titanium catalyst 1, which is used as an efficient catalyst for glyoxylate–ene reactions, is primarily composed of a µ 3 -oxo (Ti 3 O) species, for which the molecular sieves 4A employed in the catalyst preparation act as a H 2 O donor.

Article information

Article type
Paper

Chem. Commun., 1997, 281-282

Anomalous role of molecular sieves 4A in the preparation of a binaphthol-derived active µ3-oxo titanium catalyst

M. Terada, Y. Matsumoto, Y. Nakamura and K. Mikami, Chem. Commun., 1997, 281 DOI: 10.1039/A607036A

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