Issue 5, 1997

Synthesis, reactivity, X-ray crystal and molecular structures of a novel dimeric tungsten(vi) polyoxoperoxo complex: [PPh4]2[Ph2SiO2{W2 O2(µ-O2)2(O2)2 }] and of a molybdenum(vi) analogue

Abstract

Tungsten and molybdenum complexes containing a diphenylsilanediolato ligand are structurally characterised; the overall structures of the anions are conserved in organic solvents.

Article information

Article type
Paper

Chem. Commun., 1997, 473-474

Synthesis, reactivity, X-ray crystal and molecular structures of a novel dimeric tungsten(vi) polyoxoperoxo complex: [PPh4]2[Ph2SiO2{W2 O2(µ-O2)2(O2)2 }] and of a molybdenum(vi) analogue

J. Piquemal, C. Bois and J. Brégeault, Chem. Commun., 1997, 473 DOI: 10.1039/A607014K

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