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Issue 5, 1997
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Intramolecularity of the Thermal Rearrangement of Allyloxytetrazoles to N-Allyltetrazolones†

Abstract

The intramolecularity of the thermal rearrangement of 1-aryl-5-allyloxy-1H-tetrazoles 1 to 1-aryl-4-allyl-1,4-dihydrotetrazol-5-ones 2 has been investigated through cross-over studies: the results support the hypothesis for a concerted sigmatropic rearrangement occurring through a highly polar transition state, in which a partially positively charged allyl group migrates from oxygen to nitrogen, without leaving the solvent cage.

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Article type: Paper
DOI: 10.1039/A608333A
J. Chem. Res. (S), 1997, 164-165

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    Intramolecularity of the Thermal Rearrangement of Allyloxytetrazoles to N-Allyltetrazolones†

    M. Lurdes S. Cristiano and R. A. W. Johnstone, J. Chem. Res. (S), 1997, 164
    DOI: 10.1039/A608333A

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