Issue 22, 1997

Copper(I) salt mediated 1,4-reduction of α,β-unsaturated ketones using hydrosilanes

Abstract

Reduction of α,β-unsaturated ketones with HSiPhMe2 in the presence of CuF(PPh3)3·2EtOH proceeds in a 1,4-selective manner to give the corresponding saturated ketones in excellent yields.

Article information

Article type
Paper

Chem. Commun., 1997, 2159-2160

Copper(I) salt mediated 1,4-reduction of α,β-unsaturated ketones using hydrosilanes

A. Mori, A. Fujita, Y. Nishihara and T. Hiyama, Chem. Commun., 1997, 2159 DOI: 10.1039/A706032G

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