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Issue 15, 1997
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Crystal engineering: the effects of π–π interactions incopper(i) and silver(i) complexes of 2,7-diazapyrene

Abstract

The ligand 2,7-diazapyrene (L) is used to construct three- and two-dimensional arrays with Cu I and Ag I ions: {[Cu I L 2 ]PF 6 } shows an adamantoid network with three interpenetrating networks, while {[Ag I L 2 (MeCN) 2 ]BF 4 } forms linear chains of [AgL] units linked by apparent π–π stacking and Ag···Ag interactions between adjacent diazapyrene ligands to form two-dimensional sheets.

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Article type: Paper
DOI: 10.1039/A702050C
Chem. Commun., 1997, 1339-1340

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    Crystal engineering: the effects of π–π interactions in copper(i) and silver(i) complexes of 2,7-diazapyrene

    A. J. Blake, N. R. Champness, A. N. Khlobystov, D. A. Lemenovskii, W. Li and M. Schröder, Chem. Commun., 1997, 1339
    DOI: 10.1039/A702050C

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