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Issue 13, 1997
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The azido ligand: a useful tool in designing chain compounds exhibiting alternating ferro- and antiferro-magnetic interactions

Abstract

A one-pot reaction of Ni II 1, Co II 2, Fe II 3 and Mn II 4 with 2,2′-bipyridine (bipy) and azide in water leads to [M(bipy)(N 3 ) 2 ] n chains where the metal ion is alternatively bridged by double end-on (EO) and end-to-end (EE) azido bridges; theoretical analysis of the variable-temperature magnetic susceptibility data of 1 and 4 reveals the occurrence of intrachain alternating ferro- (through EO) and antiferro-magnetic (through EE) interactions.

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Article information


Chem. Commun., 1997, 1195-1196
Article type
Paper

The azido ligand: a useful tool in designing chain compounds exhibiting alternating ferro- and antiferro-magnetic interactions

G. Viau, M. Grazia Lombardi, G. De Munno, M. Julve, F. Lloret, J. Faus, A. Caneschi and J. Modesto Clemente-Juan, Chem. Commun., 1997, 1195
DOI: 10.1039/A701219E

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