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Issue 10, 1997
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Synthesis, photophysics and crystal structures of hexanuclear copper(i) and silver(i) acetylide complexes

Abstract

The luminescent complexes [M 3 (µ-Ph 2 PCH 2 PPh 2 ) 3 3 1 -C[triple bond, length as m-dash]CC 6 H 4 C[triple bond, length as m-dash]C-p)M 3 (µ-Ph 2 PCH 2 PPh 2 ) 3 ][BF 4 ] 4 are synthesized by the reaction of [M 2 (µ-Ph 2 PCH 2 PPh 2 ) 2 - (MeCN) 2 ] 2+ and 1,4-diethynylbenzene in the presence of Bu n Li in thf (M = Cu 1, Ag 2); X-ray crystal structures of both are determined.

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Article information


Chem. Commun., 1997, 963-964
Article type
Paper

Synthesis, photophysics and crystal structures of hexanuclear copper(i) and silver(i) acetylide complexes

V. Wing-Wah Yam, W. Kit-Mai Fung and K. Cheung, Chem. Commun., 1997, 963
DOI: 10.1039/A701133D

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