Issue 10, 1997
From the journal:

Chemical Communications

Oxidative addition of a C–Se bond to a PtII centre: contrasting reactions of [MCl2(PhCN)2] (M = Pd, Pt) with cyclohepteno-1,4-diselenin

C. Matthew Bates,   Pawan K. Khanna,   Christopher P. Morley  and  Massimo Di Vaira  

Abstract

The reaction of cyclohepteno-1,4-diselenin 1 with [PtCl 2 (PhCN) 2 ] proceeds via unprecedented oxidative addition of a C–Se bond to yield a platinum(IV) product, whose novel dimeric structure has been determined by X-ray crystallography; by contrast, 1 reacts with [PdCl 2 (PhCN) 2 ] to form trans-[PdCl 2 L 2 ] (L = 1).

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Article information

DOI
https://doi.org/10.1039/A607904K
Article type
Paper

Chem. Commun., 1997, 913-914

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Oxidative addition of a C–Se bond to a PtII centre: contrasting reactions of [MCl2(PhCN)2] (M = Pd, Pt) with cyclohepteno-1,4-diselenin

C. Matthew Bates, P. K. Khanna, C. P. Morley and M. Di Vaira, Chem. Commun., 1997, 913 DOI: 10.1039/A607904K

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