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Issue 24, 1997
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A new route for the synthesis of amphiphilic and water-soluble ligands: mono- and di-tertiary phosphines having an alkylene sulfate chain

Abstract

Cyclic sulfates react with LiPPh2 to form a series of new amphiphilic or water-soluble ligands: monotertiary phosphines with one or two alkylene sulfate chains and ditertiary phosphines with one or two hydrophilic tails attached to bridgehead carbon atom; the application of zwitterionic RhI complexes (sulfatephos)2Rh(cod) and (sulfatediphos)Rh(cod) in liquid biphasic catalysis has been demonstrated for the hydroformylation of styrene and oct-1-ene.

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Article type: Paper
DOI: 10.1039/A706602C
Chem. Commun., 1997, 2385-2386

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    A new route for the synthesis of amphiphilic and water-soluble ligands: mono- and di-tertiary phosphines having an alkylene sulfate chain

    H. Gulyás, P. Árva and J. Bakos, Chem. Commun., 1997, 2385
    DOI: 10.1039/A706602C

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