Accurate determinations have been made for the EPR coupling constants of 15 para-substituted benzyl radicals. These data, along with literature data for other systems have been used to reassess the stabilizing effect of para-substituents on benzylic radicals, and to throw light on the possible destabilizing effects of para F and CF3 substituents.
R. A. Jackson and M. Sharifi, J. Chem. Soc., Perkin Trans. 2, 1996, 775 DOI: 10.1039/P29960000775
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