Issue 12, 1996

Ketone-directed peracid epoxidation of cyclic alkenes

Abstract

Ketone carbonyl groups are shown to direct the peracid epoxidation of cyclic alkenes with greater selectivity than that displayed by esters. An 18O labelling study is used to show that a dioxirane intermediate is not involved in these reactions.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1996, 1373-1380

Ketone-directed peracid epoxidation of cyclic alkenes

A. Armstrong, P. A. Barsanti, P. A. Clarke and A. Wood, J. Chem. Soc., Perkin Trans. 1, 1996, 1373 DOI: 10.1039/P19960001373

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