The pentadienylsilane 9 and the dimethyl acetal 2 of isobutyraldehyde react with high (80:20)anti stereospecificity to give largely the diene 10a, which was converted into the para-disubstituted benzene 11a, having 1,6-related stereogenic centres.
I. Fleming and C. P. Leslie, J. Chem. Soc., Perkin Trans. 1, 1996, 1197 DOI: 10.1039/P19960001197
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