An acetylenic alcohol, (+)-(4E, 15E)-docosa-4,15-dien-1-yn-3-ol 1, isolated from the marine sponge Cribrochalina vasculum, was synthesized in highly enantiomerically pure form by lipase-catalysed transesterification with Novozym 435 (Candida antarctica).
T. Ohtani, K. Kikuchi, M. Kamezawa, H. Hamatani, H. Tachibana, T. Totani and Y. Naoshima, J. Chem. Soc., Perkin Trans. 1, 1996, 961 DOI: 10.1039/P19960000961
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