A new discharge nozzle for spectroscopic studies in supersonic jets

Abstract

We describe a new nozzle for spectroscopic studies of reactive species in pulsed supersonic jets. This nozzle was designed as a cheap alternative to laser ablation methods for producing metal-containing species. It employs an electrical discharge to produce metal atoms by argon ion sputtering at the cathode. These metal atoms can then be mixed with appropriate reagents to produce metal-containing species before expansion into vacuum. To avoid rapid carbon deposition onto the metal source electrode when carbon-containing reagents are used, the reactive precursor must be kept away from the metal-sputtering region. Consequently, a dual channel nozzle has been developed in which two pulsed gas sources are mixed at a common point prior to expansion. This has been tested by preparing a number of spectroscopically well characterised metal-containing species. The results show that this nozzle is a viable alternative to laser ablation for producing metal-containing species. The spectroscopic data, obtained using laser-induced fluorescence, demonstrate that the nozzle has good pulse-to-pulse stability and can maintain signal amplitude for > 80 h before electrode replenishment is required.