The high-temperature oxidation of ethylene oxide has been modelled in the temperature and pressure ranges of 1050–1400 K and 1.9–5.0 atm, respectively, with equivalence ratios, ϕ, varying from 0.5 to 2, and a mechanism of 60 steps and 30 species was assembled. A comparison of calculated and recently established measurements of the ignition delay of ethylene oxide–oxygen–argon mixtures showed very good agreement.
J. Würmel, M. McGuinness and J. M. Simmie, J. Chem. Soc., Faraday Trans., 1996, 92, 715 DOI: 10.1039/FT9969200715
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