Issue 23, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

New preparative access to and the crystal and molecular structures of cis-[PtCl2(CO)2]

Franco Bagnoli,   Daniela Belli Dell' Amico,   Fausto Calderazzo,   Ulli Englert,   Fabio Marchetti,   Gerhard E. Herberich,   Nicola Pasqualetti  and  Stefano Ramello  

Abstract

cis-Dicarbonyldichloroplatinum(II) has been found to be the thermodynamically stable species arising from: (a) carbonylation of [NBu4]2[PtCl4] in the presence of AlCl3, (b) chlorination of [PtI2(CO)2]–[Pt2I4(CO)2] with SO2Cl2 under CO and (c) carbonylation of PtCl2; the crystal and molecular structures of cis-[PtCl2(CO)2] showed a short C–O distance [average 1.115(7)Å] and intermolecular Pt ⋯ Pt and C ⋯ Cl contacts of less than 3.4 Å.

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Article information

DOI
https://doi.org/10.1039/DT9960004317
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 4317-4318

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New preparative access to and the crystal and molecular structures of cis-[PtCl2(CO)2]

F. Bagnoli, D. B. D. Amico, F. Calderazzo, U. Englert, F. Marchetti, G. E. Herberich, N. Pasqualetti and S. Ramello, J. Chem. Soc., Dalton Trans., 1996, 4317 DOI: 10.1039/DT9960004317

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