Issue 8, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Crystal structure and solution-state study of K[Al(mal)2(H2O)2]·2H2O (H2mal = malonic acid)

Andrea Tapparo,   Sarah L. Heath,   Peter A. Jordan,   Geoffrey R. Moore  and  Annie K. Powell  

Abstract

The new complex K[Al(mal)2(H2O)2]·2H2O [H2mal = CH2(CO2H)2] has been synthesized and its crystal structure determined by X-ray crystallography. An investigation of metal speciation in aqueous solution (analytical concentration around 50 mmol dm–3) by using 27Al, 1H and 13C NMR spectroscopies revealed that, in solutions at physiological pH (7.5), the bis(malonate) complex evolves to the tris(malonate), [Al(mal)3]3–, without precipitation of aluminium hydroxide.

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Article information

DOI
https://doi.org/10.1039/DT9960001601
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 1601-1606

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Crystal structure and solution-state study of K[Al(mal)2(H2O)2]·2H2O (H2mal = malonic acid)

A. Tapparo, S. L. Heath, P. A. Jordan, G. R. Moore and A. K. Powell, J. Chem. Soc., Dalton Trans., 1996, 1601 DOI: 10.1039/DT9960001601

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