SCHEDULED MAINTENANCE
Deprotonation of enantiomerically enriched secondary benzyl ether tricarbonylchromium(0) complexes (96–99% ee) with tert-butyllithium followed by quenching with a range of electrophiles gives tertiary benzyl ether tricarbonylchromium(0) complexes of high enantiomeric purity (92–98.5% ee) in good yield (65–94%) with overall retention of configuration.
S. E. Gibson (née Thomas), P. C. V. Potter and M. H. Smith, Chem. Commun., 1996, 2757 DOI: 10.1039/CC9960002757
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