Issue 23, 1996
From the journal:

Chemical Communications

Activation of a ring methyl substituent in pentamethylcyclopentadienyl rhenium(V) compounds: synthesis and characterization of the 1,2,3,4-tetramethyl-5,6-dihydrofulvene-5,6-dithiolato complex [ReO{(S)(SCH2)C5Me4}(C5Me5)]

Max Herberhold,   Guo-Xin Jin  and  Arnold L. Rheingold  

Abstract

Reaction of the half-sandwich rhenium(V) complexes [ReCl4(C5Me5)] or [Re(O)Cl2(C5Me5)] with H2S in chloroform in the presence of pyridine leads to the chiral dithiolato complex [ReO{(S)(SCH2)C5Me4}(C5Me5)]1.

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Article information

DOI
https://doi.org/10.1039/CC9960002645
Article type
Paper

Chem. Commun., 1996, 2645-2646

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Activation of a ring methyl substituent in pentamethylcyclopentadienyl rhenium(V) compounds: synthesis and characterization of the 1,2,3,4-tetramethyl-5,6-dihydrofulvene-5,6-dithiolato complex [ReO{(S)(SCH2)C5Me4}(C5Me5)]

M. Herberhold, G. Jin and A. L. Rheingold, Chem. Commun., 1996, 2645 DOI: 10.1039/CC9960002645

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