Issue 22, 1996

Synthesis and structure of {[Gd(OSO)3(µ-F2AsF4)6/2]·0.25SO2}m

Abstract

Oxidation of lanthanide metals with AsF5 in liquid SO2 yields the corresponding polymeric {[M(SO2)n](AsF6)3}m(1a–j, M = Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb) where the metal centres are bridged by AsF6 units; the X-ray crystal structure of the Gd complex 1g is reported.

Article information

Article type
Paper

Chem. Commun., 1996, 2593-2594

Synthesis and structure of {[Gd(OSO)3(µ-F2AsF4)6/2]·0.25SO2}m

J. Petersen, E. Lork and R. Mews, Chem. Commun., 1996, 2593 DOI: 10.1039/CC9960002593

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