The first structurally characterized organometallic nitrosyl porphyrin: structure of [Ru(ttp)(NO)(C6H4F-p)](ttp =meso-tetratolylporphyrinato dianion)
Abstract
Reaction of [Ru(ttp)(NO)Cl] with aryl or alkyl Grignard reagents gives [Ru(ttp)(NO)R](R = C6H4F-p, Me); the Ru–C bond in [Ru(ttp)(NO)Me] undergoes insertion by SO2, and the structure of [Ru(ttp)(NO)(C6H4F-p)] is determined by X-ray crystallography.