The titanium silicate molecular sieve, TS-1, exchanged with an aqueous solution of K2CO3 is an excellent heterogeneous catalyst for the synthesis of dimethyl carbonate by an ester exchange reaction between ethylene carbonate and methanol.
T. Tatsumi, Y. Watanabe and K. A. Koyano, Chem. Commun., 1996, 2281 DOI: 10.1039/CC9960002281
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