Formation of a nickel(II) complex with a new N2S2 macrocyclic ligand by C–Cl bond cleavage and C–S bond formation
Abstract
Heating a monohelical square-planar nickel(II) complex containing chlorine atoms in the side arms gives a distorted octahedral nickel(II) complex containing the trans-N2S2 macrocyclic ligand by carbon–chlorine bond cleavage and carbon–sulfur bond formation.