The reactions of 2,6-disubstituted aryl carbene complexes with alkynes give hydrindenone products if a phenol function is present which prevents aromatization to an indene product by a tautomerization of a metal complexed vinyl alcohol intermediate.
M. E. Bos, W. D. Wulff and K. J. Wilson, Chem. Commun., 1996, 1863 DOI: 10.1039/CC9960001863
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