The biohydroxylation of 1-substituted adamantanes using Absidia cylindrospora in a whole-cell oxidation system exclusively generated 3-hydroxy and 4ax-hydroxy derivatives; the assignments were confirmed by three X-ray crystal structure determinations.
P. D. Bailey, S. D. Higgins, C. H. Ridyard, S. M. Roberts, G. M. Rosair, R. A. Whittaker and A. J. Willetts, Chem. Commun., 1996, 1833 DOI: 10.1039/CC9960001833
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