N,N′-Bis(3,5-di-tert-butylsalicylidene)ethylenediamine H2L reacts with [Y{N(SiHMe2)2}3(thf)2] in thf–hexane at ambient conditions to afford monomeric [YL{N(SiHMe2)2}(thf)], the X-ray structure determination of which reveals a strongly bent coordination mode of the anionic salen derived ligand.
O. Runte, T. Priermeier and R. Anwander, Chem. Commun., 1996, 1385 DOI: 10.1039/CC9960001385
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