The first rhodium enantioselective catalysts for the Diels–Alder reaction between methacrolein and cyclopentadiene are described; the molecular structure of the catalyst precursor [(η5-C5Me5)Rh(R-Prophos)(H2O)][SbF6]2 is also presented.
D. Carmona, C. Cativiela, R. García-Correas, F. J. Lahoz, M. P. Lamata, J. A. López, M. P. L. De Víu, L. A. Oro, E. S. José and F. Viguri, Chem. Commun., 1996, 1247 DOI: 10.1039/CC9960001247
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