The square-planar nickel(II) complex of 6,6-bis(4-hexylbenzoylamino)-2,2′-bipyridine mediates up-hill transport of carbobenzoxyhistidine (Cbz-His) across an organic liquid membrane by affinity switching of the axial coordination of the imidazole unit of Cbz-His to the metal centre.
S. Lee, H. Yamada, S. Mishina and K. Araki, Chem. Commun., 1996, 1179 DOI: 10.1039/CC9960001179
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