The metallated complex [Ru(tbp)(tpy)][PF6][Htbp = 6-(2-thienyl)-2,2′-bipyridine, tpy = 2,2′:6′,2″-terpyridine] is converted to the non-metallated species [Ru(Htbp)(tpy)][PF6] containing an N,N,S-bonded Htbp ligand upon treatment with acid; this process is reversed upon reaction of [Ru(Htbp)(tpy)][PF6] with aqueous sodium hydroxide solution.
E. C. Constable, S. J. Dunne, D. G. F. Rees and C. X. Schmitt, Chem. Commun., 1996, 1169 DOI: 10.1039/CC9960001169
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