Ti-, V-, Cr-, Mo-, and Mn-substituted hexagonal mesoporous silicas prepared at ambient temperature by electrostatic (S+ X–I+) and neutral (S0 I0) surfactant templating pathways are catalytically active for the peroxide hydroxylation of benzene to phenol in the absence of a solvent.
W. Zhang, J. Wang, P. T. Tanev and T. J. Pinnavaia, Chem. Commun., 1996, 979 DOI: 10.1039/CC9960000979
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